Free Distilling Tools

Pot Still Distillation Simulator

Configure your wash, set heat input and spirit style, then run a real-time ethanol-water batch distillation in your browser. Watch the temperature rise from ambient to bubble point, vapour strength peak and fall, and cuts progress from heads into hearts and tails — all modelled on Van Laar VLE thermodynamics and a proper energy balance.

Run clock
00:00
Head temp
22.0C
Vapor ABV
0.0%
Boiler ABV
10.0%
Collected
0.00L
Rate
0.00L/h

Animated pot still

Heat, boiling, vapor travel, condenser flow and receiver drip respond to actual collection rate.

Startup
START

Receiver cuts

Cut timing uses recovered ethanol progress, spirit style, vapour ABV and temperature.

Heads
0.000 L
Hearts
0.000 L
Tails
0.000 L
Spent
0.000 L
This simulator is educational. It is not a safety, legal or process validation tool. Real cuts depend on equipment, wash composition, process operation and sensory judgment.

Live distillation curves

Hover any chart for exact values. Click to expand full run history. VLE diagram shows live operating point on the equilibrium curve.

Temperature vs time
C over minutes
Distillate ABV vs time
percent ABV over minutes
Boiler ABV vs time
percent ABV over minutes
Collection volume vs time
L over minutes
VLE x-y diagram
Liquid → vapour ethanol mole fraction
Methanol in distillate
mg/L — relative volatility, not a safety threshold

How to use this simulator

The simulator runs a full pot still batch distillation from ambient temperature to the end of the run. Every parameter affects the physics.

  1. Set your wash. Enter boiler volume and wash ABV. A typical sugar wash is 8–12%, a grain wash 6–9%, and a fruit wash 8–14%.
  2. Choose a spirit style. Each preset adjusts cut thresholds — vodka uses the tightest hearts window, brandy the widest. Pot efficiency and cut timing adjust automatically.
  3. Set heat input. A 2–3 kW element is typical for home use. Higher heat produces more vapour per hour but can reduce separation quality.
  4. Set methanol ppm. Sugar washes are typically 50–300 ppm; fruit washes can be 500–3,000 ppm. The methanol chart shows relative depletion through the run for transparency — cut on taste, smell and the acetaldehyde-driven harshness of the first fraction, not on a methanol number.
  5. Click Start. Use the speed slider (1–50×) to run at pace. The animated still, all six charts, and the fraction jars update in real time.
  6. Open Advanced for realism. Set your local atmospheric pressure (altitude lowers boiling point), a thermometer error if yours reads off, ambient room temperature and still insulation (change heat-up time, not the boiling point), and theoretical plates if your still has a dephlegmator, packing or a tall column above the pot.
  7. Export or review. When the run ends a summary card shows yield, estimated bottles and methanol discarded. Export CSV to analyse the full run data.

Detailed calculation model

This simulator uses a dynamic batch pot-still model grounded in real thermodynamics: ethanol concentration falls, vapour strength declines, head temperature rises from ambient to bubble point, production rate responds to heat input, and the run progresses from heads into hearts and tails.

1. Boiler inventory

The boiler tracks ethanol, water and methanol volumes separately. As product is collected, each component is removed according to its instantaneous vapour composition, conserving total moles at each timestep.

2. Van Laar VLE

Activity coefficients use the Van Laar model (A₁₂ = 1.6798, A₂₁ = 0.9227), more accurate than 2-suffix Margules near the azeotrope. Bubble-point temperature is solved numerically via bisection at each step, giving a realistic temperature curve throughout the run.

3. Theoretical plates

The pot itself is stage 1, limited by pot efficiency (imperfect boil and vapour-liquid contact). Setting theoretical plates above 1 in Advanced adds further ideal Van Laar equilibrium stages on top — a dephlegmator, packing, or a tall lyne arm — cascading the stage-1 vapour upward and re-equilibrating at each stage, the same way a real column pushes composition further toward the azeotrope with each additional plate. A fractional plate count interpolates between the last full stage and the next, matching the 1.1–1.3 typical for a real pot still. This directly re-uses the same VLE model rather than a fixed relative-volatility shortcut, so separation naturally weakens near the azeotrope the way real columns do. Methanol tracking is not re-staged by this cascade in this version.

4. Thermal-mass heat-up

Temperature rises as dT/dt = (Q·η − Q_loss) / (m·Cp), where m is boiler mass and Cp is the mixture heat capacity. Q_loss is a lumped wall heat-loss term set by the gap between current temperature and ambient, scaled down by the insulation setting — a simplified stand-in for a full per-surface heat-transfer model, not a claim of matching that level of detail. At default settings (20°C ambient, 50% insulation) a 25 L boiler at 2.4 kW takes roughly 55–65 minutes to reach bubble point, in line with real distillery experience; a bare, uninsulated still or a cold room noticeably slows this down.

5. Energy-balance vapour rate

Vapour rate is derived from Q_vap = Q_in × ε_still, divided by the mixture latent heat ΔHvap (ethanol 841 kJ/kg, water 2260 kJ/kg, weighted by distillate composition). Rate naturally decreases as ethanol depletes and more energy goes into vaporising water.

6. Methanol (3rd component)

Methanol is tracked as a dilute 3rd component using its own Antoine equation and a fixed activity coefficient (γ = 2.2). It is more volatile than ethanol and depletes earlier in the run, but not sharply enough for a small foreshots cut to remove it entirely — some carries into heads and hearts regardless of cut size. The chart is shown for transparency about relative volatility, not as a foreshots safety cutoff. The real reason to discard the first fraction is acetaldehyde and other highly volatile congeners, not methanol quantity.

7. Cut classification

Cuts use spirit-specific profiles based on the DistilCalc cuts calculator. The primary driver is recovered ethanol progress, with vapour ABV and temperature used as guardrails to prevent misclassification during heat-up and late-run decay.

Ptotal = γE xE PsatE(T) + γW xW PsatW(T)  |  yE = γE xE PsatE(T) / Patm
ln γE = A₁₂ / (1 + A₁₂ xE / A₂₁ xW)²  |  ln γW = A₂₁ / (1 + A₂₁ xW / A₁₂ xE)²
Stage N: xN = yN₋₁  |  yN = f_VLE(xN)  |  dT/dt = (Q·η − Q_loss) / (m·Cp)  |  Q̇_vap = Q·ε / ΔHvap(xE)  |  yM ≈ γM xM PsatM / Patm

The simulator solves the temperature at which total pressure reaches your local atmospheric pressure (1013 hPa at sea level by default), then calculates ethanol vapour mole fraction from modified Raoult's law and converts that back to a condensed liquid ABV. This captures the full distillation curve — from the steep early rise to the gradual tailing-off as the hearts window closes.

  • Whisky: balanced pot-still profile, keeping moderate congeners for grain character.
  • Rum: slightly wider hearts, allowing more late character for heavier styles.
  • Brandy: wider and lower cuts — fruit spirits retain more character deeper into the run.
  • Gin: clean, tight profile to avoid solventy or heavy notes masking botanicals.
  • Vodka: narrowest hearts window, prioritising neutrality and a clean spirit.

The speed slider goes to 50×. Internally the simulator divides each animation frame into small calculation steps, so high-speed settings are less likely to skip past the hearts window.

Whisky Tasting Journal: Pair your simulated runs with real batch records. 100 structured entries, score /100, buy-again rating. 6 x 9 in, 116 pages, cream paper.

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Frequently asked questions

The VLE (vapour-liquid equilibrium) diagram plots ethanol mole fraction in the vapour phase (y-axis) against the liquid phase (x-axis). Every point above the 45° diagonal line means the vapour is richer in ethanol than the liquid — this enrichment is the entire basis of distillation. The diagram shows a live operating point moving along the equilibrium curve as the run progresses, and marks the azeotrope (~89.4 mol%) where no further enrichment is possible regardless of additional distillation passes.

Not entirely, and that is a common misconception. Methanol boils at 64.7°C, a little below ethanol's 78.4°C, so it is somewhat more volatile and depletes from the boiler earlier in the run. But its relative volatility to ethanol is not extreme enough for a small foreshots cut to remove it all — some methanol carries into the heads and even the hearts regardless of cut size. The real reason to discard the first fraction is acetaldehyde and other highly volatile congeners, which spike hard in the first few minutes and are what actually cause the harsh, solventy character foreshots are known for. This simulator's methanol chart tracks relative depletion for transparency, not as a safety threshold.

In a pot still run, foreshots and heads come first — they contain aldehydes, methanol and light esters and are discarded or added back to the next run. Hearts are the clean central fraction: the spirit you keep. Tails come last and contain fusel oils and heavier congeners; they can be recycled. The transition between fractions is gradual, not a sharp line — which is why sensory evaluation by taste and smell is the gold standard for making cuts in practice.

The simulator uses established thermodynamic models — Van Laar activity coefficients, Antoine vapour pressures, a thermal-mass heat-up equation and an energy-balance vapour rate — that produce plausible, physically consistent results. Real runs differ because of still geometry, heat distribution, wash composition, operator technique and reflux behaviour that the model does not capture. This tool is for education and planning, not process validation. Always verify cuts by taste and smell.

Yes — click the Export CSV button in the charts panel to download the full run history. The file includes time (minutes), temperature, distillate ABV, boiler ABV, collection volume, vapour rate, and methanol concentration at every recorded timestep. It opens directly in Excel or any spreadsheet tool.

The simulation speed slider goes up to 50×. At that rate a full 25 L whisky run (which takes 3–4 hours in real life) completes in a few minutes. Internally the simulator divides each animation frame into many small calculation steps, so even at high speeds the physics model doesn't skip over the hearts window. Set the slider to 1× to see the run at true real-time scale.

Yes. Lower atmospheric pressure at altitude reduces the boiling point of both water and ethanol, which shifts the whole temperature curve down without changing the ABV curve much. Set your local pressure in the Advanced panel — sea level is 1013 hPa, and it drops by roughly 12 hPa per 100 m of elevation. For a dedicated altitude correction, see the Vapor Temperature Calculator.

Mainly for how long heat-up takes, not the boiling point itself — boiling point is set by pressure, not room temperature. A cold room and a bare, uninsulated still lose more heat to the surroundings, so a larger share of the heat input goes into replacing that loss instead of raising the temperature, stretching out the heat-up phase. Once a rolling boil is reached, the model tracks boiling point against pressure the same way regardless of ambient conditions.

A theoretical plate is one full equilibrium separation stage. A simple pot still with no rectification is 1 plate. A real pot still typically behaves like 1.1 to 1.3 plates depending on lid shape and riser length, because some incidental reflux happens in the neck. Adding a dephlegmator, packing, or a taller column pushes this higher, moving the distillate composition further toward the ethanol-water azeotrope with each additional stage — and with diminishing returns as it gets closer, the same way real columns behave. Set this in the Advanced panel above 1 to model that extra rectification.

References

Primary and peer-reviewed sources for the technical claims on this page.

  1. Chemistry LibreTexts. Fractional Distillation of Non-ideal Mixtures (Azeotropes). Cited for: Ethanol and water form a minimum-boiling azeotrope at 95.6% ethanol by mass, boiling at 78.2°C, which is the ceiling for separation by distillation alone.
  2. Brady, J.B., Smith College, Department of Geosciences. Equilibrium diagram for H₂O–ethanol mixtures. Cited for: An independent phase diagram placing the ethanol-water azeotrope at 95.6% ethanol by weight and 78.17°C, based on Evans (1916) experimental data.

Formulas verified against primary sources, August 2026.

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